Fabrication and conductance characterization of single C-60 molecular junction in solutions

Guo, Y; Kiguchi, M; Zhao, JW; Murakoshi, K

HERO ID

857582

Reference Type

Journal Article

Year

2009

HERO ID 857582
In Press No
Year 2009
Title Fabrication and conductance characterization of single C-60 molecular junction in solutions
Authors Guo, Y; Kiguchi, M; Zhao, JW; Murakoshi, K
Journal Chemical Physics Letters
Volume 477
Issue 1-3
Page Numbers 189-193
Abstract The conductance and stretching length of the single C-60 molecule bridging two Au electrodes (C-60 molecular junction) were studied in air, mesitylene and 0.1 M HClO4 solution. In air, the C-60 molecular junction did not show any well-defined conductance value. In either mesitylene or HClO4 solution, the systems showed a conductance value of 0.01G(0). The stretching length of the single C-60 molecular junction was determined to be 0.01 nm. The values of the conductance and stretching length in solution were smaller than those obtained in ultra high vacuum, indicating the weak C-60-Au interaction in solution. Considering the particular shape of the C-60 molecule and the junction formation process in the present system, a sliding model was proposed to interpret the observation. (C) 2009 Published by Elsevier B. V.
Doi 10.1016/j.cplett.2009.06.084
Wosid WOS:000268329800039
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword chemistry, physical; physics, atomic, molecular & chemical
Is Qa No