SOLVENT AND TEMPERATURE EFFECT IN THE LIVING RING OPENING ε-CAPROLACTONE/Cp2 ZrHCl POLYMERIZATION

Asandei, AD; Saha, G; Simpson, CP

HERO ID

994922

Reference Type

Journal Article

Year

2010

HERO ID 994922
In Press No
Year 2010
Title SOLVENT AND TEMPERATURE EFFECT IN THE LIVING RING OPENING ε-CAPROLACTONE/Cp2 ZrHCl POLYMERIZATION
Authors Asandei, AD; Saha, G; Simpson, CP
Journal Polymer Preprints (American Chemical Society, Division of Polymer Chemistry)
Volume 51
Page Numbers 528
Abstract The article focuses on a study which examined various solvents such as diglyme, toluene and mesitylene for the synthesis of high molecular weight living ring opening ε-caprolactone polymerization. It is noted that the polymerization mechanism employed coordinative anionic type and is the same to that of conventional metal alkoxides.
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