Ambient temperature vapor pressure and adsorption capacity for (perfluorooctyl) ethylene, 3-(perfluorobutyl)propanol, perfluorohexanoic acid, ethyl perfluorooctanoate, and perfluoro-3,6-dioxaheptanoic acid

Schindler, BJ; Buchanan, JH; Mahle, JJ; Peterson, GW; Glover, TG

HERO ID

3859926

Reference Type

Journal Article

Year

2013

Language

English

HERO ID 3859926
In Press No
Year 2013
Title Ambient temperature vapor pressure and adsorption capacity for (perfluorooctyl) ethylene, 3-(perfluorobutyl)propanol, perfluorohexanoic acid, ethyl perfluorooctanoate, and perfluoro-3,6-dioxaheptanoic acid
Authors Schindler, BJ; Buchanan, JH; Mahle, JJ; Peterson, GW; Glover, TG
Journal Journal of Chemical and Engineering Data
Volume 58
Issue 6
Page Numbers 1806-1812
Abstract With increased use of highly fluorinated compounds has come an increased need for knowledge of the fundamental properties of these chemicals, such as vapor pressure, to determine how they will behave in the environment and how to remove them. A modified vapor saturation method was used to measure the ambient temperature vapor pressure of 3-(perfluorobutyl)propanol, (perfluorooctyl)ethylene, perfluorohexanoic acid, ethyl perfluorooctanoate, and perfluoro-3,6-dioxaheptanoic acid between (254.15 and 309.15) K. The freezing point for perfluorohexanoic acid was determined to be between (291.15 and 293.15) K The vapor pressures, which ranged from (0.87 to 978) Pa, were used to generate saturated vapor streams of the compound so that adsorption capacities on BPL activated carbon could be determined. Adsorption equilibrium data for three of the chemicals, measured at a feed concentration of 139 mu L.L-1 at high and low relative humidity, are presented and discussed.
Doi 10.1021/je400205g
Wosid WOS:000320641100049
Url https://pubs.acs.org/doi/10.1021/je400205g
Is Certified Translation No
Dupe Override No
Comments Scopus URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84879079888&doi=10.1021%2fje400205g&partnerID=40&md5=2fc6813b0a9ad7836ab79697f2dbcd9d
Is Public Yes
Language Text English