NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

1002273

Reference Type

Journal Article

Title

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

Author(s)

Fulmer, GR; Miller, AJM; Sherden, NH; Gottlieb, HE; Nudelman, A; Stoltz, BM; Bercaw, JE; Goldberg, KI

Year

2010

Is Peer Reviewed?

Journal

Organometallics
ISSN: 0276-7333
EISSN: 1520-6041

Volume

Issue

Page Numbers

2176-2179

Language

English

DOI

10.1021/Om100106e

Web of Science Id

WOS:000277212300025

URL

http://pubs.acs.org/doi/abs/10.1021/om100106e
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Abstract

Tables of (1)H and (13)C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents. Building upon the work of Gottlieb, Kotlyar, and Nudelman in the Journal of Organic Chemistry, signals for common impurities are now reported in additional NMR solvents (tetrahydrofuran-d(8), toluene-d(8), dichloromethane-d(2), chlorobenzene-d(5), and 2,2,2-trifluoroethanol-d(3)) which are frequently used in organometallic laboratories. Chemical shifts for other organics which are often used as reagents or internal standards or are found as products in organometallic chemistry are also reported for all the listed solvents.

Keywords

CHEMISTRY, INORGANIC & NUCLEAR; CHEMISTRY, ORGANIC