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HERO ID
1003879
Reference Type
Journal Article
Title
Low-temperature catalytic combustion of chlorobenzene over MnOx–CeO2 mixed oxide catalysts
Author(s)
Wang, X; Kang, Q; Li, D
Year
2008
Is Peer Reviewed?
Yes
Journal
Catalysis Communications
ISSN:
1566-7367
Volume
9
Issue
13
Page Numbers
2158-2162
DOI
10.1016/j.catcom.2008.04.021
Web of Science Id
WOS:000257973600003
URL
http://linkinghub.elsevier.com/retrieve/pii/S1566736708001702
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Abstract
Mno(x)-CeO2 mixed oxide catalysts prepared by sol-gel method were tested for the catalytic combustion of chlorobenzene (CB), as a model of chlorinated aromatic volatile organic compounds (CVOCs). MnOx-CeO2 catalysts with the different ratio of Mn/Ce + Mn were found to possess high catalytic activity for catalytic combustion of CB, and MnOx(0.86)-CeO2 was the most active catalyst, on which the complete combustion temperature (T-90%) of chlorobenzene was 236 degrees C. The stability of MnOx-CeO2 catalysts in the CB combustion was investigated. MnCx-CeO2 catalysts with high Mn/Ce + Mn ratios present high stable activity, which is related to their high ability to remove Cl species adsorbed and a large amount of active surface oxygen. (C) 2008 Elsevier B.V. All rights reserved.
Keywords
chlorinated VOCs; chlorobenzene; MnOx-CeO2; CeO2; catalytic combustion
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