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HERO ID
1559475
Reference Type
Journal Article
Title
Determination of the rate constant of the reaction of NO3 with C2H5I using time-resolved cavity ring-down spectroscopy
Author(s)
Nakano, Y; Hosho, Y; Sadamori, K; Ishiwata, T
Year
2012
Is Peer Reviewed?
Yes
Journal
Chemical Physics Letters
ISSN:
0009-2614
Volume
535
Page Numbers
26-29
DOI
10.1016/j.cplett.2012.03.040
Web of Science Id
WOS:000303437900005
Abstract
The reaction of NO3 with C2H5I was studied using time resolved cavity ring-down spectroscopy. The rate constant of NO3 + C2H5I reaction was determined
to be (2.4 +/- 0.4) x 10 (13) cm(3) molecule (1) s (1) at 298 K and showed no pressure dependence
in the range of 25-100 Torr of N-2 diluent. The determined value of the rate constant suggests
that the reaction of NO3 with C2H5I would play an important role in the iodine cycle at night.
(C) 2012 Elsevier B. V. All rights reserved.
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