US EPA

1565262 

Journal Article 

Synthesis and optical characterization of pure and Cu doped SnO2 thin films deposited by spray pyrolysis 

Roy, SS; Podder, J 

2010 

Yes 

Journal of Optoelectronics and Advanced Materials
ISSN: 1454-4164 

12 

7 

1479-1484 

WOS:000281042700008 

Pure tin oxide (SnO2) and copper (Cu) doped SnO2 thin films
have been deposited from tin chloride (SnCl2) and cupric nitrate Cu(NO3)(2) precursors onto glass
substrates by spray pyrolysis technique at the substrate temperature of 350 square C. The doping
concentration of Cu was varied from 1 to 8 wt. % while all other deposition parameters such as
spray rate, carrier air gas pressure and distance between spray nozzle to substrate were kept
constant. The surface morphology and optical properties of the as-deposited thin films have been
studied by Scanning Electron Microscopy (SEM) attached with an EDX and UV visible spectroscopy.
The transmittance for the as-deposited films was recorded in the wavelength range of 290 to 1100
nm. The optical transmission of the films was found to increase from 71 % to 80 % for initial
doping of Cu up to 4% for 200 nm thickness and then decreased for higher level of copper doping.
The optical band gap of undoped film was found to be 3.75 eV and it was shifted to 3.50 eV for 4
wt. % of Cu doping and then increased on further increasing the concentration of the dopants.
This paper discusses the optical properties of the as-deposited SnO2 films with Cu doping. 

Spray pyrolysis; Tin oxide; SEM; EDX; Optical band gap