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1592365 
Journal Article 
A photo Lewis acid generator (PhLAG): controlled photorelease of B(C6F5)3 
Khalimon, AY; Piers, WE; Blackwell, JM; Michalak, DJ; Parvez, M 
2012 
Yes 
Journal of the American Chemical Society
ISSN: 0002-7863
EISSN: 1520-5126 
134 
23 
9601-9604 
English 
22651906 
WOS:000305107800017 
A molecule that releases the strong organometallic Lewis acid B(C(6)F(5))(3) upon irradiation with 254 nm light has been developed. This photo Lewis acid generator (PhLAG) now enables the photocontrolled initiation of several reactions catalyzed by this important Lewis acid. Herein is described the synthesis of the triphenylsulfonium salt of a carbamato borate based on a carbazole function, its establishment as a PhLAG, and the application of the photorelease of B(C(6)F(5))(3) to the fabrication of thin films of a polysiloxane material. 
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