Transition metals in organic synthesis, part 87: An efficient palladium-catalyzed route to 2-oxygenated and 2,7-dioxygenated carbazole alkaloids - Total synthesis of 2-methoxy-3-methylcarbazole, glycosinine, clausine L, mukonidine, and clausine V | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

1594508

Reference Type

Journal Article

Title

Transition metals in organic synthesis, part 87: An efficient palladium-catalyzed route to 2-oxygenated and 2,7-dioxygenated carbazole alkaloids - Total synthesis of 2-methoxy-3-methylcarbazole, glycosinine, clausine L, mukonidine, and clausine V

Author(s)

Forke, R; Krahl, MP; Daebritz, F; Jager, A; Knoelker, HJ

Year

2008

Is Peer Reviewed?

Journal

Synlett
ISSN: 0936-5214
EISSN: 1437-2096

Issue

Page Numbers

1870-1876

DOI

10.1055/s-2008-1078508

Web of Science Id

WOS:000258030400026

Abstract

Optimization of the palladium(II)-catalyzed oxidative
cyclization of N,N-diarylamines opens up the way to an efficient synthesis of 2-oxygenated and
2,7-dioxygenated carbazole alkaloids including 2-methoxy-3-methylcarbazole, glycosinine, clausine
L, mukonidine, and clausine V.

Keywords

alkaloids; antibiotics; catalysis; cyclizations; palladium