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HERO ID
1596387
Reference Type
Journal Article
Title
New tetraphenylethylene-containing conjugated polymers: Facile synthesis, aggregation-induced emission enhanced characteristics and application as explosive chemsensors and PLEDs
Author(s)
Wu, W; Ye, S; Tang, R; Huang, L; Li, Q; Yu, Gui; Liu, Y; Qin, J; Li, Z
Year
2012
Is Peer Reviewed?
1
Journal
Polymer
ISSN:
0032-3861
Volume
53
Issue
15
Page Numbers
3163-3171
DOI
10.1016/j.polymer.2012.05.035
Web of Science Id
WOS:000306151100012
Abstract
In this paper, tetraphenylethylene (TPE) units, one of the
typical aggregation-induced emission (AIE) moieties, are utilized to construct a new functional
polyfluorene (PF) P1, which exhibited the exciting property of the aggregation-induced emission
enhancement (AIEE), instead of the aggregation-caused quenching (ACQ) of normal PFs, and could
probe the explosive with high sensitivity both in the nano-particles and solid state. Three other
TPE-containing polymers, P2-P4, were also successfully prepared, and demonstrated good
performance as explosive chemosensors and light-emitting materials. P3, bearing carbazole as
hole-transporting units showed the best performance with a maximum luminance efficiency of 1.17
cd/A and a maximum brightness of 3609 cd/m(2) at 12.9 V in its light-emitting diode device. (C)
2012 Elsevier Ltd. All rights reserved.
Keywords
Tetraphenylethylene (TPE); Aggregation-induced emission enhancement (AIEE); Functional polyfluorene
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