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HERO ID
1620458
Reference Type
Journal Article
Title
Au/Fe3O4 and Au/Fe2O3 Catalysts: Physicochemical Properties and Oxidation of CO and Propane
Author(s)
Grzybowska, B; Ruszel, M; Samson, K; Grabowski, R; Spiridis, N; Freindl, K; Korecki, J
Year
2009
Is Peer Reviewed?
1
Journal
Polish Journal of Chemistry
ISSN:
0137-5083
Volume
83
Issue
12
Page Numbers
2129-2136
Web of Science Id
WOS:000274494500010
Abstract
Catalysts containing Au deposited on Fe3O4 (commercial
Cerac) and on Fe2O3 were synthesized, characterized by XPS, XRD, Mossbauer spectroscopy, H2TPR,
isopropanol decomposition - a probe reaction of acid-base properties, and tested in oxidation of
CO and C3H8. Au//Fe3O4 catalyst, containing a mixture of magnetite and maghemite (gamma-Fe2O3)
phases, was found to be more acidic containing more surface OH groups and less reducible than
Au/alpha-Fe2O3 (hematite). The activity in oxidation of CO and propane was higher for Au/alpha-
Fe2O3 catalyst as compared with Au/Fe3O4.
Keywords
Au/FeOx catalysts: physicochemical properties; oxidation of CO; oxidation of propane
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