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1622212 
Journal Article 
Enthalpies and entropies of dissolution and dissociation of benzoic acid in EtOH-H2O and i-PrOH-H2O mixtures 
Hu, XG; Lin, RS; Zong, HX 
1999 
Yes 
Acta Physico - Chimica Sinica
ISSN: 1000-6818 
15 
9 
838-844 
WOS:000082640200013 
In this paper, the dissolution and dissociation enthalpies
of benzoic acid in ethanol-water and isopropanol-H2O mixtures have been determined by two kinds
of microcalorimeters respectively. Combined with the corresponding Gibbs function changes
existing in the literature, the dissolution and dissociation entropies have been calculated.
Great efforts have been made to interpret the characteristic variations of the transfer
enthalpies and entropies according to the skin phase model for solute-solvent interactions and
the structure alteration of the mixed solvents. 
benzoic acid; mixed solvent; dissolution enthalpy; dissociation enthalpy; skin phase model