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HERO ID
1629478
Reference Type
Journal Article
Title
Synthesis and Characterization of Alkyl Polyglucosides Quaternary Ammonium Salt
Author(s)
Niu, H; Lou, PJ; Ding, H; Zhu, HJ; Wang, LC
Year
2010
Is Peer Reviewed?
Yes
Journal
Jingxi Huagong
ISSN:
1003-5214
Volume
27
Issue
11 (Nov 2010)
Page Numbers
1055-1059
Abstract
N-(3-Chlorine-2-hydroxypropyl)-N, N-dimethyl-N-dodecyl-ammonium chloride (CHPDDAC) was synthesized with N, N-dimethyl dodecyl amine hydrochlorate and epichlorohydrin. Then, alkyl polyglucosides (APG) was quaternizing modified into alkyl polyglucosides quaternary ammonium salt(APGQAS) by CHPDDAC. The effects on the reaction process were investigated by the orthogonal experiment. The optimum conditions of the APGQAS were obtained as follows: isopropyl alcohol as solvent, n(APG): n (CHPDDAC) = 1.1 = 1, reaction temperature 80 degree C, reaction time 7 h. The structure of APGQAS was characterized by FTIR spectrum, elementary analysis and super(1)HNMR. The surface activities of the product were measured, the critical micelle concentration(CMC) was 3.16 x 10 super(-4)mol/L, surface tension was 21.51 mN/m, Krafft point was -3.57 degree C.
Keywords
Temperature; Chlorides; Ammonium Salts; Surface Tension; Ammonium; Solvents; Alcohols; Synthesis
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