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1664077 
Journal Article 
Continuous hydrogen production via the steam-iron reaction by chemical looping in a circulating fluidized-bed reactor 
Ryden, M; Arjmand, M 
2012 
Yes 
International Journal of Hydrogen Energy
ISSN: 0360-3199 
37 
6 
4843-4854 
WOS:000301990100010 
The steam-iron reaction was examined in a two-compartment fluidized-bed reactor at 800-900 degrees C and atmospheric pressure. In the fuel reactor compartment, freeze-granulated oxygen carrier particles consisting of Fe3O4 supported on inert MgAl2O4 were reduced to FeO with carbon monoxide or synthesis gas. The reduced particles were transferred to a steam reactor compartment, where they were oxidized back to Fe3O4 by steam, while at the same time producing H-2. The process was operated continuously and the particles were transferred between the reactor compartments in a cyclic manner. In total, 12 h of experiments were conducted of which 9 h involved H-2 generation. The reactivity of the oxygen carrier particles with carbon monoxide and synthesis gas was high, providing gas concentrations reasonably close to thermodynamic equilibrium, especially at lower fuel flows. The amount of H-2 produced in the steam reactor was found to correspond well with the amount of fuel oxidized in the fuel reactor, which suggests that all FeO that was formed were also re-oxidized. Despite reduction of the oxygen carrier to FeO, defluidization or stops in the solid circulation were not experienced. Used oxygen carrier particles exhibited decreased BET specific surface area, increased bulk density and decreased particle size compared to fresh. This indicates that the particles were subject to densification during operation, likely due to thermal sintering. However, stable operation, low attrition and absence of defluidization were still achieved, which suggest that the overall behaviour of the oxygen carrier particles were satisfactory. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. 
Steam-iron process; Chemical-looping combustion; Chemical-looping reforming; Hydrogen; Iron oxide