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HERO ID
1666303
Reference Type
Journal Article
Title
Volatilization kinetics of zinc and lead in Zn-Pb-bearing dust pellets containing carbon
Author(s)
Wang, DY; Shen, XL; Gu, DR; Sha, GY
Year
2000
Page Numbers
297-311
Web of Science Id
WOS:000177472600027
Abstract
The study of the volatilization kinetics of zinc and lead in pellets made of zinc-lead-bearing dust mixed with coal powder, in a nitrogen atmosphere and at a temperature range between 1100 degreesC and 1300 degreesC, shows that the reduction temperature has a significant effect on the volatilization rates of zinc and lead, and that both the particle size of the coal powder and the extra carbon content has no effect on the volatilization rates. The obtained activation energies for the volatilization of zinc and lead are 79.42kJ/mol and 88.74kJ/mol respectively. The volatilization rate of zinc is controlled by the reaction between the zinc oxide and carbon monoxide while that of lead is controlled by the lead evaporation reaction, and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.
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