A NEW LITHIUM HYDROGEN SULFATE, LI-2(HSO4)(2)(H2SO4) - SYNTHESIS AND CRYSTAL-STRUCTURE | Health & Environmental Research Online (HERO)

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Citation
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HERO ID

1705195

Reference Type

Journal Article

Title

A NEW LITHIUM HYDROGEN SULFATE, LI-2(HSO4)(2)(H2SO4) - SYNTHESIS AND CRYSTAL-STRUCTURE

Author(s)

Werner, C; Kemnitz, E; Troyanov, S; Strutschkov, YT; Worzala, H

Year

1995

Is Peer Reviewed?

Journal

Zeitschrift fuer Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Volume

621

Issue

Page Numbers

1266-1269

Web of Science Id

WOS:A1995RJ99100027

Abstract

The title compound crystallizes in good shaped single crystals from the system lithium sulfate/sulfuric acid in the orthorhombic space group Peen, unit cell parameters a = 17.645(4), b = 5.378(1), c = 10.667(3) Angstrom. V = 1012.2 Angstrom(3), Z = 4, D-x = 2.009 g cm(-3).

There are two types of SO4 tetrahedra, SO3(OH) and SO2(OH)(2), connected via hydrogen bonds forming layers parallel to the xy-plane. The layers are linked by Li atoms, which are tetrahedral coordinated by O atoms coming two by two from neighboured layers.

Keywords

LITHIUM HYDROGEN SULFATE DIHYDROGEN SULFATE; SYNTHESIS; CRYSTAL STRUCTURE