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1737391 
Journal Article 
The removal of styrene using a dielectric barrier discharge (DBD) reactor and the analysis of the by-products and intermediates 
Zhang, H; Li, Kan; Sun, T; Jia, J; Yang, X; Shen, Y; Wang, Jun; Lou, Z 
2013 
1 
Research on Chemical Intermediates
ISSN: 0922-6168
EISSN: 1568-5675 
SPRINGER 
DORDRECHT 
39 
3 
1021-1035 
WOS:000316008300019 
As a kind of volatile organic compound, styrene is a typical industrial pollutant with high toxicity and odorous smell. In this study, the removal of malodorous styrene simulation waste gas was carried out in a self-made wire-tube dielectric barrier discharge reactor. The decomposition efficiency of the reaction was investigated under different applied voltages and flow rates. The results showed that nearly 99.6 % of styrene could be removed with a concentration of 3,600 mg/m(3) and the applied voltage of 10.8 kV. However, the selectivity of CO2 and CO showed that the mineralization efficiency of styrene was less than 25 %. The by-products of the reaction, including O-3, NO (x) and other intermediates, were also detected and analyzed under different applied voltages. The relationships between the applied voltage and the quantity of final product (CO2) and by-products (intermediate organics, NO (x) , O-3) were investigated. The reaction mechanism was also described according to the bond energy and the intermediates that formed. 
VOCs; Styrene; Dielectric barrier discharge; Intermediates