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1739523 
Journal Article 
Decomposition of methane over iron catalysts at the range of moderate temperatures: The influence of structure of the catalytic systems and the reaction conditions on the yield of carbon and morphology of carbon filaments 
Ermakova, MA; Ermakov, DY; Chuvilin, AL; Kuvshinov, GG 
2001 
Yes 
Journal of Catalysis
ISSN: 0021-9517
EISSN: 1090-2694 
Elsevier 
201 
2 
183-197 
WOS:000170172200003 
Decomposition of high-purity methane in the presence of alpha -Fe-based catalysts to produce filamentous carbon was investigated. The reaction was studied in the temperature range of 650 to 800 degreesC. Filamentous carbon was demonstrated to form at temperatures not lower than 680 degreesC in the presence of both bare alpha -Fe and catalysts based thereon with admixtures of various hard-to-reduce oxides (SiO(2), Al(2)O(3), ZrO(2), and TiO(2)). The maximal carbon yield, 45 g per g of iron, was obtained with the Fe/SiO(2) catalyst comprising silica in amounts of 15 wt%. XRD and high-resolution electron microscopy were used for studying the carbon deposits. The data obtained allowed the conclusion on the essential influence of the chemical nature of the hard-to-reduce oxide admixture in the iron catalyst on the microstructure and morphology of the carbon filaments. Depending on the admixture, specific shapes of filaments and nanotubes predominated. Carbon nanotubes with thin walls built up by coaxial cylindrical graphene layers were formed in large amount over the Fe/Al(2)O(3) catalyst. Centers of growth of octopus-like nanotubes were observed. (C) 2001 Academic Press. 
methane decomposition; filamentous carbon; iron catalysts; carbon yield; carbon nanotubes; octopus carbon