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HERO ID
1745372
Reference Type
Journal Article
Title
Degradation of cathode current-collecting materials for anode-supported flat-tube solid oxide fuel cell
Author(s)
Kim, J; Song, R; Chung, D; Hyun, SH; Shin, DR
Year
2009
Is Peer Reviewed?
Yes
Journal
Journal of Power Sources
ISSN:
0378-7753
Volume
188
Issue
2
Page Numbers
447-452
DOI
10.1016/j.jpowsour.2008.11.144
Web of Science Id
WOS:000264646900014
Abstract
Different types of cathode current-collecting material for anode-supported flat-tube solid oxide fuel cells are fabricated and their electrochemical properties are characterized. Current collection for the cathode is achieved by winding Ag wire and by painting different conductive pastes of Ag-Pd, Pt, La(0.6)Sr(0.4)CoO(3) (LSCo), and La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) (LSCF) on the wire. Cell performance at the initial operation time is in the order of Pt > LSCo > LSCF > Ag-Pd. On the other hand, the performance degradation rate is in the order of LSCo < LSCF < Pt < Ag-Pd. LSCo paste as a cathode current-collector shows the most stable long-term performance of 0.8 V, 300 mA cm (2) at 750 C, even under a thermal cycle condition with heating and cooling rates of 150 Ch (1). The performance degradation of the Ag-Pd and Pt pastes is caused by increased polarization resistance clue to metal particle sintering. From these results, it is concluded that a cathode current-collector composed of wound silver wire with LSCo paste is useful for anode-supported flat-tube cells as it does not experience any significant degradation during a long operation time. (C) 2009 Published by Elsevier B.V.
Keywords
Solid oxide fuel cell; Anode-supported flat-tube; Cathode current-collecting materials; Performance degradation; Polarization resistance
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