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HERO ID
1786970
Reference Type
Journal Article
Title
New coordination motifs of melamine directed by N-H---X (X = Cl or Br) hydrogen bonds
Author(s)
Zhang, L; Zhang, J; Li, ZJ; Cheng, JK; Yin, PX; Yao, YG
Year
2007
Is Peer Reviewed?
Yes
Journal
Inorganic Chemistry
ISSN:
0020-1669
EISSN:
1520-510X
Volume
46
Issue
15
Page Numbers
5838-5840
Language
English
PMID
17592837
DOI
10.1021/ic7005138
Abstract
Unusual mu(2)- and mu(3)-coordination modes of melamine are found in two organic-inorganic hybrid copper halides, [Cu(2)Br(2)(MA)](n) (1) and [Cu(3)Cl(3)(MA)](n) (2) (MA = melamine), in which the MA ligand affords two N-heterocycle N atoms to link (Cu(2)Br(2))infinity stairs and serves as a novel mu(3) bridge to give a 3D framework, respectively.
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