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HERO ID
1866625
Reference Type
Journal Article
Title
3-Nitroso-2,4,6,8-tetraphenyl-3,7-diazabicyclo[3.3.1]nonan-9-one
Author(s)
Natarajan, S; Mathews, R
Year
2011
Is Peer Reviewed?
Yes
Journal
Acta Crystallographica. Section E: Structure Reports Online
ISSN:
1600-5368
Volume
67
Issue
Pt 7
Page Numbers
O1686-U683
Language
English
PMID
21837083
DOI
10.1107/S1600536811022203
Web of Science Id
WOS:000294663200056
Abstract
In the title compound, C(31)H(27)N(3)O(2), the two piperidine rings fused to each other each adopt a slightly distorted chair conformation. The phenyl rings on the N-unsubstituted piperidine ring occupy an equatorial position, while those on the N-nitroso-substituted piperidine ring are in axial positions. The NO group is approximately coplanar with the piperidine ring with a maximum deviation of 0.048 (4) Å. The dihedral angles between the mean planes of the axially and equatorially oriented phenyl rings are 27.7 (1) and 31.9 (1)°, respectively. Mol-ecular packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯π inter-actions.
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