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Citation
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HERO ID
192380
Reference Type
Technical Report
Title
Updated maximum incremental reactivity scale for regulatory applications
Author(s)
Carter, WPL
Year
1998
Publisher
Air Pollution Research Center and College of Engineering, Center for Environmental Research and Technology
Location
University of California, Riverside CA
Abstract
This preliminary report presents an updated version of the Maximum Incremental Reactivity (MIR)and other reactivity scales which has been developed using a new version of the SAPRC chemical mechanism. The scales were calculated essentially the same approach and airshed scenarios as used previously (Carter, 1994a), except that the chemical mechanism has been completely updated, many new classes of VOCs have been added. Estimates of relative uncertainties and upper limit reactivities are also presented.
The reactivity scale presented in this report has been developed for use by the California Air Resources Board (CARB) for various regulatory applications. The initial application is expected to be a
proposal to incorporate reactivity-based adjustments in some VOC content standards for consumer products. In these regulations, it is proposed that "best estimate" MIR’s will be used when determining
baselines for product categories, and that "uncertainty adjusted" MIR’s will be used when determining whether a product is in compliance with the reactivity-adjusted standard. Therefore, this report includes tabulations of both the "best estimate" and "uncertainty adjusted" MIRs, along with related VOC-specific
information relevant to uncertainty and the status of the mechanism employed. This includes reactivities calculated using other scales, indications of generally how the VOC was represented in the model, and footnotes indicating the status and uncertainty of the mechanism and reactivity estimates for the various VOC classes. Reactivities of selected mineral spirits and exhaust mixtures are also given.
Details documenting the updates to the general mechanism, the development of the mechanisms for the new classes of VOCs, and the development of the new reactivity scales will be given in reports
which are in preparation (Carter, 1998; Carter et al, 1998). It should be recognized that although the mechanism and reactivities presented in this preliminary report are intended to be the completed versions, the possibility that corrections or adjustments may be appropriate before the mechanism and scales are
finalized cannot be ruled out. Therefore, these results must be considered to be preliminary.
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