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Citation
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HERO ID
1958840
Reference Type
Journal Article
Title
The Synthesis of eta-1,2,3,4,5,6-Hexafluorocyclohexane (Benzene Hexafluoride) from Benzene
Author(s)
Durie, AJ; Slawin, AMZ; Lebl, T; O'Hagan, D
Year
2012
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Book Title
Angewandte Chemie
Volume
51
Issue
40
Page Numbers
10086-10088
Language
English
PMID
22968946
DOI
10.1002/anie.201205577
Web of Science Id
WOS:000309181700022
URL
http://doi.wiley.com/10.1002/anie.201205577
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Abstract
Six of the best: Benzene had been used by Faraday and Mitscherlich in their respective synthesis of hexachloro- and hexabromocyclohexane in the early 19th century. Also starting from benzene, η-1,2,3,4,5,6- hexafluorocyclohexane (benzene hexafluoride; see X-ray structure of a dimer) was now synthesized in five steps. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
benzene hexafluoride; conformational analysis; hexafluorocyclohexane; organofluorine chemistry
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