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2066259 
Technical Report 
Nonchemical Surface Treatment for Aluminum Alloys 
Koch, GH; Todd, GL; Deutchman, A; Partyka, R 
1996 
NTIS/03012274_a 
GRA and I 
GRA and I 
The state-of-the-art chemical surface treatments for adhesive bonding of aluminum alloys, such as phosphoric acid anodizing (PAA) are the basis of the present high-strength and durable adhesive bonds. Because of increasingly strict regulations on the use of wet chemicals, the Materials Directorate at Wright Laboratories initiated a research program to develop alternative nonchemical techniques that do not produce waste and are not detrimental to health and environment. This report describes the development of a nonchemical process, based on ion beam enhanced deposition (IBED). The process consists of various steps, the major ones being grit blasting with 50 micrometers Al2O3 grit and deposition of (proportional to) - Al2O3 with IBED. The resulting surface is dense and corrosion resistant, and provides an excellent basis for adhesive bonding. Strength and durability studies on peel and wedge type specimens is equivalent to that of anodized specimens. Surface analytical studies, Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), Fourier Transform Infrared Spectroscopy (FTIR) , and Atomic Force Microscopy (AFM), as well as electrochemical studies were used to characterize the surface and determine the mechanism of adhesion.