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Citation
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HERO ID
2273953
Reference Type
Journal Article
Title
Adsorption of Mercury on Activated Carbon in Simulated Flue Gas with Continuous Components Change
Author(s)
Hu, CX; Zhou, JinS; Li, JXin; Wang, YC; Zheng, J; Xu, MeiJ; Luo, ZY; Cen, KeFa
Year
2013
Is Peer Reviewed?
Yes
Journal
Asian Journal of Chemistry
ISSN:
0970-7077
EISSN:
0975-427X
Volume
25
Issue
15
Page Numbers
8765-8768
Web of Science Id
WOS:000325204200120
Abstract
This paper focused on the influence of flue gas component change on elemental mercury (Hg-0) adsorption by powder activated carbon from apricot's shell and discussed the Hg-0 adsorption characteristics and mechanism of activated carbon. Experimental results showed that activated carbon from apricot's shell had no Hg-0 adsorption ability in the non-oxidizing atmosphere, such as N-2, N-2 + CO2 etc. Though the influence on homogeneous oxidation reaction of Hg-0 was limited, NO2 was the key factor on heterogeneous catalytic oxidation reaction of Hg-0 on the surface of activated carbon. It was easy to form NO2 by reaction between the NO and O-2. It could also enhance the Hg-0 adsorption ability of activated carbon through preloading NO2 on the surface. Based on these experimental results, it finely proved that Hg-0 adsorption by activated carbon was a heterogeneous catalytic oxidation reaction.
Keywords
Apricot shell; Activated carbon; Elemental mercury; Oxidization; Chemical adsorption
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