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2291119 
Journal Article 
HIGH THERMAL ENERGY STORAGE DENSITY LiNO3-NaNO3-KNO3-NO2 QUATERNARY MOLTEN SALT FOR PARABOLIC TROUGH SOLAR POWER GENERATION 
Wang, T; Mantha, D; Reddy, RG 
2012 
73-84 
A new eutectic LiNO3-NaNO3-KNO3-KNO2 quaternary molten salt system was calculated using thermodynamic modeling. The eutectic temperature was predicted to be 100 degrees C. The melting point and heat capacity of the salt eutectic composition were determined using DSC. The experimentally determined melting point is in excellent agreement with the predicted value. The melting point is more than 124 degrees C lower than that of the KNO3-NaNO3 solar salt. The density of the molten salt was experimentally determined as function of temperature. Using the density, heat capacity and the melting point, thermal energy storage density and gravimetric storage density of the quaternary molten salt were calculated and compared with that of solar salt. The larger storage density value of this molten salt indicates that this salt has a better energy storage capacity for solar power generation systems. 
DSC; LiNO3-NaNO3-KNO3-KNO2 quaternary system; melting point; heat capacity; thermodynamic properties; density; thermal energy storage density