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HERO ID
2291510
Reference Type
Journal Article
Title
Nitroxide-catalyzed transition-metal-free aerobic oxidation processes
Author(s)
Wertz, S; Studer, A
Year
2013
Is Peer Reviewed?
Yes
Journal
Green Chemistry
ISSN:
1463-9262
EISSN:
1463-9270
Volume
15
Issue
11
Page Numbers
3116-3134
DOI
10.1039/c3gc41459k
Web of Science Id
WOS:000327052700015
Abstract
Advances in the field of transition-metal-free nitroxide-catalyzed aerobic oxidation processes are covered in this critical review. Along with the relevant physical properties of nitroxides, their application as oxidation catalysts by using dioxygen as a reagent or terminal oxidant will be discussed. The second part of the review focuses on the use of TEMPO-based nitroxides as catalysts for aerobic alcohol oxidation. Mechanistic studies will also be addressed (130 references).
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