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HERO ID
2309938
Reference Type
Journal Article
Title
Absorption and biodegradation of hydrophobic volatile organic compounds: determination of Henry's constants and biodegradation levels
Author(s)
Darracq, G; Couvert, A; Couriol, C; Amrane, A; Le Cloirec, P
Year
2009
Is Peer Reviewed?
1
Journal
Water Science and Technology
ISSN:
0273-1223
EISSN:
1996-9732
Volume
59
Issue
7
Page Numbers
1315-1322
Language
English
PMID
19380996
DOI
10.2166/wst.2009.124
Abstract
Biodegradation of three volatile organic compounds (VOCs) was studied. Toluene, dimethylsulphide (DMS), and dimethyldisulphide (DMDS) were introduced into flasks filled with emulsions of Di-2-EthylHexylAdipate (DEHA) in water, containing biomass (activated sludge). The VOC concentrations were analysed in the gas, organic and aqueous phases, and compared to the initial VOC quantities introduced in order to deduce their consumption by biomass. Toluene and DMDS were completely consumed, and then removed from the gas and the organic phases, except when DEHA and water are in the same volume ratio, which appears to be extreme environmental conditions for bacterial growth. The high DMS volatility resulted in an important gas loss, leading to a lower amount of DMS available for activated sludge growth. For all the VOC experiments, some components, characteristics of the DEHA degradation, including 2-ethylhexanal, 2-ethylhexanol, 2-ethylhexanoic acid and adipic acid, were identified.
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