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Citation
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HERO ID
2639046
Reference Type
Journal Article
Title
Sustainable Recycling of Benzoic Acid Production Waste: Green and Highly Efficient Methods To Separate and Recover High Value-Added Conjugated Aromatic Compounds from Industrial Residues
Author(s)
Zhang, Xin; Qiao, P; Ji, X; Han, J; Liu, L; Weeks, BL; Yao, Q; Zhang, Z
Year
2013
Volume
1
Issue
8
Page Numbers
974-981
DOI
10.1021/sc400059J
Web of Science Id
WOS:000322863100014
Abstract
Industrial residues formed in the industrial production of benzoic acid by cobalt-catalyzed oxidation of toluene are traditionally disposed as waste materials and often burnt or buried. It therefore may become a significant source of environmental pollution. In this report, we describe simple techniques to obtain high value conjugated aromatic compounds, including 9-fluorenone, 6H-benzo[c]chromen-6-one, biphenyl-3-carboxylic acid, and biphenyl-4-carboxylic acid, from benzoic acid industrial residue using inexpensive alkalis and acids. The separation methods involve simple and mild procedures with high economic effectiveness and low environmental contamination.
Keywords
Sustainable chemistry; Benzoic acid industrial residue; 9-Fluorenone; 6H-Benzo[c]chromen-6-one; Biphenyl carboxylic acids
Tags
IRIS
•
Cobalt
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