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2648309 
Journal Article 
Durability test of PEMFC with Pt-PFSA composite membrane 
Liu, Z; Yang, Y; Lu, W; Wang, C; Chen, M; Mao, Z 
2012 
Yes 
International Journal of Hydrogen Energy
ISSN: 0360-3199 
37 
1 
956-960 
WOS:000300470000110 
Self-humidifying proton exchange membrane fuel cell (PEMFC) has aroused quite many interests because this kind of fuel cell system is so simple that only air blower is needed to supply reacting and cooling air. Composite membrane with Pt particles embedded in perfluorosulfonate acid (Pt-PFSA) resin exhibits good self-humidifying fuel cell performance, while the inorganic Pt particles destroy the integrality of the organic PFSA membrane and the durability of this kind of membrane is questionable. In this paper, Pt-PFSA composite membrane was prepared and the durability of the membrane in midterm fuel cell operation was tested and compared with PFSA membrane. Two single cells with 25 cm(2) active area were assembled with Pt-PFSA membrane and PFSA membrane, and continuously operated at constant current density of 500 mA/cm(2), 50 degrees C, with dry H-2 and dry air for 1000 h. Polarization curves, cyclic voltammetry and AC impedance analysis were conducted during the durability test. The results reveal that the Pt-PFSA cell shows better stability in fuel cell performance than the PFSA cell, while the hydrogen crossover current density increases about 100 times, which indicates much faster corrosion speed of the Pt-PFSA membrane than the PFSA membrane during the mid-term continuous fuel cell operation. The experimental results illustrate that much more efforts are needed to be focused on the integrity and degradation prevention of the Pt-PFSA membrane, although it shows excellent mid-term self-humidifying performance. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. 
Durability; Self-humidified; Pt-PFSA composite membrane; PEMFC