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2660708 
Journal Article 
Theoretical modeling of air electrode operating in SOFC mode and SOEC mode: The effects of microstructure and thickness 
Li, W; Shi, Y; Luo, Yu; Cai, N 
2014 
Yes 
International Journal of Hydrogen Energy
ISSN: 0360-3199 
39 
25 
13738-13750 
WOS:000341343200088 
A theoretical model of solid oxide cells coupled with heterogeneous elementary reactions, electrochemical reactions, electrode microstructure and mass and charge transport is developed and validated. The effects of microstructure, thickness and temperature of air electrode on the cell performance in both solid oxide electrolysis cell (SOEC) and solid oxide fuel cell (soFq are individually discussed. The simulation results indicate that the growth in the thickness of air electrode reduces the effect of particle diameter while dramatically enlarges the effect of porosity. The microstructure and thickness of air electrode and temperature have significantly different impacts on solid oxide cells operating in SOEC mode and SOFC mode. The results indicate that the optimizing strategy of air electrode for SOEC and SOFC should be different especially for a thicker air electrode. The proposed model can be a useful tool for bridging the electrode geometry and microstructure design and optimization. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. 
Solid oxide fuel cell; Solid oxide electrolysis cell; Elementary reaction model; Air electrode; Microstructure; Thickness