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HERO ID
2665800
Reference Type
Journal Article
Title
Zeolite Y synthesized with FCC spent catalyst fines: particle size effect on catalytic reactions
Author(s)
Liu, X; Li, L; Yang, T; Yan, Z
Year
2012
Is Peer Reviewed?
Yes
Journal
Journal of Porous Materials
ISSN:
1380-2224
Volume
19
Issue
1
Page Numbers
133-139
DOI
10.1007/s10934-011-9534-1
Web of Science Id
WOS:000301187400016
Abstract
In this study, Y zeolite with different particle sizes was synthesized with fines of Fluid Catalytic Cracking (FCC) spent catalyst. The effect of particle size on physicochemical properties of zeolite was systematically investigated. The results showed that zeolites synthesized via in situ crystallization technique exhibited large surface area, high relative crystallinity and high thermal stability. With a decrease of particle size of zeolite, both total acid density and B acid sites increased while acid L sites decreased. The cracking activity for heavy oil and coke resistance of ultrafine zeolite catalysts were enhanced. Of note is that the desulfurization capability of superfine zeolite catalyst was found to be much higher than that of industrial catalyst.
Keywords
Particle size effect; FCC spent catalyst fines; Zeolite Y; Cracking activity
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