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HERO ID
2665809
Reference Type
Journal Article
Title
Enabling catalysis of Ru-CeO2 for propane oxidation in low temperature solid oxide fuel cells
Author(s)
Liu, X; Zhan, Z; Meng, Xie; Huang, W; Wang, S; Wen, T
Year
2012
Is Peer Reviewed?
Yes
Journal
Journal of Power Sources
ISSN:
0378-7753
Volume
199
Page Numbers
138-141
DOI
10.1016/j.jpowsour.2011.09.072
Web of Science Id
WOS:000298269700018
Abstract
This paper reports on integration of a supported thin film catalyst as a reformer, consisting of nano-scale ruthenium particles well dispersed in the ceria matrix, into the anode chamber of a ceria-electrolyte solid oxide fuel cells (SOFCs). Operation on the propane-air fuel mixture yields maximum power densities of 395 mW cm(-2), 280 mW cm(-2) and 160 mW cm(-2) at 500,450 and 400 degrees C, respectively. In comparison, the output power densities drop to 298 mW cm(-2) at 500 degrees C and <10 mW cm(-2) at 450 degrees C in the absence of the catalyst layer. The substantially enhanced performance can be explained by the high catalytic activity of the Ru-CeO2 layer for propane partial oxidation reactions, producing higher amount of hydrogen available for the fuel cell operation and thereby reducing the anodic polarization resistance. (C) 2011 Elsevier B.V. All rights reserved.
Keywords
Low temperature solid oxide fuel cells; Catalyst; Partial oxidation; Propane; Hydrocarbons
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