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Citation
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HERO ID
2809754
Reference Type
Journal Article
Title
(E)-4-(Benz-yloxy)benzaldehyde thio-semicarbazone
Author(s)
Tarafder, MT; Islam, MA; Crouse, KA; Chantrapromma, S; Fun, HK
Year
2008
Is Peer Reviewed?
Yes
Journal
Acta Crystallographica. Section E: Structure Reports Online
ISSN:
1600-5368
Volume
64
Issue
Pt 6
Page Numbers
o988-o989
Language
English
PMID
21202714
DOI
10.1107/S1600536808012671
Abstract
In the title compound, C(15)H(15)N(3)OS, the thio-semicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thio-semicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benz-yloxy and phenyl rings is 72.48 (5)°. In the crystal structure, mol-ecules are inter-connected by N-H⋯N and N-H⋯S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by π-π inter-actions [centroid-centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C-H⋯π inter-actions.
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