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HERO ID
2838468
Reference Type
Journal Article
Title
Deterioration rate of hardened cement caused by high concentrated mixed acid attack
Author(s)
Miyamoto, S; Minagawa, H; Hisada, M
Year
2014
Is Peer Reviewed?
Yes
Journal
Construction and Building Materials
ISSN:
0950-0618
EISSN:
1879-0526
Volume
67
Page Numbers
47-54
DOI
10.1016/j.conbuildmat.2013.11.008
Web of Science Id
WOS:000343390500009
Abstract
The purposes of this study are to clarify the deterioration mechanism of hardened cement caused by high concentrated acid attack. As the result, In the case of high concentrated pure acid, deterioration rate varies greatly according to the kind of product of the attack of acid. This behavior can be explained by solubility of product. Next, in the case of which mixed acids containing H2SO4, HCl or HNO3 is attacking on hardened cement, the deterioration rate begins to increase when H2SO4 molar fraction decreases from between about 0.7 and 0.4-0.0. This behavior can be explained by chemical kinetics. (C) 2013 Elsevier Ltd. All rights reserved.
Keywords
Sulfuric acid; Hydrochloric acid; Nitric acid; Deterioration rate; Molar fraction; Chemical kinetics
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