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2840832 
Journal Article 
Mechanisms of Nitric Oxide Reactions Mediated by Biologically Relevant Metal Centers 
Ford, PC; Pereira, JCM; Miranda, KM 
2014 
Structure and Bonding (Berlin)
ISSN: 0081-5993 
Structure and Bonding 
154 
99-135 
Here, we present an overview of mechanisms relevant to the formation and several key reactions of nitric oxide (nitrogen monoxide) complexes with biologically relevant metal centers. The focus will be largely on iron and copper complexes. We will discuss the applications of both thermal and photochemical methodologies for investigating such reactions quantitatively. 
Copper; Heme models; Hemes; Iron; Metalloproteins; Nitric oxide