Synthesis, characterization and antimicrobial studies of mono and bimetallic trinuclear transition metal complexes of bis(N-2,N-2 '-acetylacetonehydrazonato)-N-1,N-1 '-benzil dihydrazone (BAHBD) with Cu-II, Ni-II and Co-II ions | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

2845102

Reference Type

Journal Article

Title

Synthesis, characterization and antimicrobial studies of mono and bimetallic trinuclear transition metal complexes of bis(N-2,N-2 '-acetylacetonehydrazonato)-N-1,N-1 '-benzil dihydrazone (BAHBD) with Cu-II, Ni-II and Co-II ions

Author(s)

Das, PK; Panda, AK; Panda, A; Behera, NK; Tripathy, SK

Year

2014

Is Peer Reviewed?

Yes

Journal

Journal of the Indian Chemical Society
ISSN: 0019-4522

Volume

Issue

Page Numbers

1867-1875

Web of Science Id

WOS:000350330000003

Abstract

A few mono and bimetallic trinuclear metal complexes of the type [MCuM(BAHBD)(2)X-2(H2O)(4)], where M = Cu-II, Ni-II, Co-II; X = Cl, Br, NO3 and BAHBD = bis(N-2,N-2'-acetylacetonehydrazonato)-N-1,N-1'-benzil dihydrazone have been isolated in a stepwise reaction from the precursor Copper bis(benzil dihydrazone) complex. These have been characterized on the basis of elemental analysis, spectral and magnetic properties, conductivity measurements and thermal analyses. The ligand as well as the metal complexes exhibited good antimicrobial activities against the pathogenic fungus Aspergillus niger, Helminthosporium oryzae and Fusarium oxysporium.

Keywords

Trinuclear metal complex; fungicidal screening; thermal analysis; electronic spectra