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HERO ID
2870038
Reference Type
Journal Article
Title
Alternating-current electrolysis for the production of phenol from benzene
Author(s)
Lee, B; Naito, H; Nagao, M; Hibino, T
Year
2012
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Book Title
Angewandte Chemie
Volume
51
Issue
28
Page Numbers
6961-6965
Language
English
PMID
22684819
DOI
10.1002/anie.201202159
Web of Science Id
WOS:000305990800029
URL
https://www.proquest.com/docview/1516685377?accountid=171501&bdid=64565&_bd=o4Ve%2FZ9I%2FKOWukYiP0vbUGQ4IcQ%3D
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Abstract
Works both ways: phenol was produced by both anodic and cathodic benzene oxidations over the V(x)O(y)-Sn(0.9)In(0.1)P(2)O(7) electrode in an electrochemical cell, thus allowing the use of AC electrolysis for phenol production. AC electrolysis was found to be more efficient and selective toward phenol production than DC electrolysis.
Keywords
active oxygen species; alternating-current electrolysis; benzene; oxidation; phenol
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