Direct phenol synthesis by selective oxidation of benzene with molecular oxygen on an interstitial-N/Re cluster/zeolite catalyst | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

2883567

Reference Type

Journal Article

Title

Direct phenol synthesis by selective oxidation of benzene with molecular oxygen on an interstitial-N/Re cluster/zeolite catalyst

Author(s)

Bal, R; Tada, M; Sasaki, T; Iwasawa, Y

Year

2006

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Volume

Issue

Page Numbers

448-452

Language

English

PMID

16323233

DOI

10.1002/anie.200502940

Web of Science Id

WOS:000234604400019

URL

http://doi.wiley.com/10.1002/anie.200502940
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Abstract

(Chemical Equation Presented) Remarkable selectivity (88% in the steady-state reaction and 94% in the pulse reaction) is observed in the direct synthesis of phenol from benzene with molecular oxygen over a Re/zeolite catalyst prepared by chemical-vapor deposition. The novel interstitial-N/Re clusters are formed with NH3 and are essential for the activity in the selective oxidation reaction. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

chemical vapor deposition; cluster compounds; heterogeneous catalysis; oxidation; zeolites