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2886476 
Journal Article 
Carbocycle synthesis through facile and efficient palladium-catalyzed allylative de-aromatization of naphthalene and phenanthrene allyl chlorides 
Lu, S; Xu, Z; Bao, M; Yamamoto, Y 
2008 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
47 
23 
4366-4369 
English 
18442153 
WOS:000256364400019 
(Chemical Equation Presented) Ring of truth: The palladium-catalyzed reaction of allyltributylstannane with naphthalene or phenanthrene derivatives bearing an allyl chloride group proceeds smoothly to provide de-aromatized products with unique structures (see scheme). These products are very stable and can be used as intermediates to give fused-ring systems. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. 
de-aromatization; naphthalenes; palladium; phenanthrenes; synthetic methods