CATALYTIC PROPERTIES OF RHENIUM OXIDE SYSTEMS IN THE OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE AND CYCLOHEXANE | Health & Environmental Research Online (HERO)

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HERO ID

2910841

Reference Type

Journal Article

Title

CATALYTIC PROPERTIES OF RHENIUM OXIDE SYSTEMS IN THE OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE AND CYCLOHEXANE

Author(s)

Belomestnykh, IP; Shakhnovich, GV; Rozhdestvenskaya, NN; Ryashentseva, MA; Isagulyants, GV

Year

1987

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Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

905-908

Language

English

DOI

10.1007/BF00956333

Web of Science Id

WOS:A1987L705400005

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250103921&doi=10.1007%2fBF00956333&partnerID=40&md5=661ae15a8f5fc20b730223d3db0156ce
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Abstract

1. The oxidative dehydrogenation of ethylbenzene and cyclohexane on rhenium oxide catalysts proceeds 10-30 times more rapidly than simple dehydrogenation. 2. Rhenium oxide and the oxidative condensation products (OCP) act additively in the oxidative dehydrogenation of ethylbenzene to increase the conversion of this hydrocarbon and the yield of styrene. 3. The addition of rhenium oxide to vanadium-magnesium systems increases their activity and selectivity in the oxidative dehydrogenation of ethylbenzene and suppresses extensive oxidative reactions. 1987 Plenum Publishing Corporation.