Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework - the iron(III) complex with benzene-1,3,5-tricarboxylate | Health & Environmental Research Online (HERO)

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HERO ID

3072498

Reference Type

Journal Article

Title

Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework - the iron(III) complex with benzene-1,3,5-tricarboxylate

Author(s)

Sotnik, SA; Kolotilov, SV; Kiskin, MA; Dobrokhotova, ZhV; Gavrilenko, KS; Novotortsev, VM; Eremenko, IL; Imshennik, VK; Maksimov, YuV; Pavlishchuk, VV

Year

2014

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Journal

Russian Chemical Bulletin
ISSN: 1066-5285
EISSN: 1573-9171

Volume

Issue

Page Numbers

862-869

Language

English

DOI

10.1007/s11172-014-0522-x

Web of Science Id

WOS:000348593900011

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84918793971&doi=10.1007%2fs11172-014-0522-x&partnerID=40&md5=fbd0b57ffc695f20b42e5b931e511d46
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Abstract

A new iron(III) coordination compound with the benzene-1,3,5-tricarboxylate anion of the composition [Fe-2(III)(OH)(0.3)(H2O)(1.7)(btc)(4/3)]Cl-1.7 center dot 2.8DMF center dot 1.9H(2)O (1) was synthesized. Its crystal structure was determined, and the Mossbauer spectra were analyzed. The adsorption of salicylaldehyde and nitromethane by compound 1 was studied. The adsorption kinetics of salicylaldehyde is described by the pseudo-second order equation. The diffusion of this aldehyde in particles of compound 1 is, most probably, the rate-limiting step in the Henry reaction.

Keywords

metal-organic framework; iron(III); benzene-1,3,5-tricarboxylate; X-ray diffraction; Mossbauer spectroscopy; sorption; sorption kinetics; Henry reaction