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3106298 
Journal Article 
pi-Allyl palladium methodology for selective deprotection of allylamines. Practical synthesis of secondary amines 
Lemaireaudoire, S; Savignac, M; Dupuis, C; Genet, JP 
1995 
Yes 
Bulletin de la Société Chimique de Paris
ISSN: 0037-8968 
132 
11 
1157-1166 
WOS:A1995TN25500012 
The palladium-promoted deallylation of allylamines derived from primary and secondary amines is achieved with high to quantitative yield in the presence of 2-mercaptobenzoic acid as an allyl scavenger. This method was used for the sequential cleavage of diallylamines. A. synthetic application of this procedure is presented in the preparation of secondary amines from diallylamines. 
allylamine; deallylation; sequential deprotection; pi-allyl palladium complexes; 2-mercaptobenzoic acid; substitution of amines