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3109508 
Journal Article 
Palladium nanoparticles supported on nitrogen-doped carbon spheres as enhanced catalyst for ethanol electro-oxidation 
Li, Y; Yao, Li; Zhang, LinQun; Liu, AnRan; Zhang, YJ; Liu, SQin 
2014 
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
ISSN: 0022-0728 
730 
65-68 
In this paper, nitrogen-doped carbon spheres (NCSs) were prepared as a new catalyst support for ethanol electro-oxidation through carbonization of poly(o-phenylenediamine) spheres. The NCS-supported palladium nanocatalyst exhibited higher current density and better stable life for ethanol electro-oxidation in alkaline media than palladium catalysts supported on activated carbon and nitrogen-doped carbon nanotubes. The catalytic current of the palladium/NCS composite was even comparable to commercial platinum catalyst (40 wt% Pt loading). (C) 2014 Elsevier B.V. All rights reserved. 
Palladium nanoparticle; Nitrogen-doped carbon sphere; Ethanol electro-oxidation