Health & Environmental Research Online (HERO)


Print Feedback Export to File
3159397 
Journal Article 
Crystal structure of the bora-benzene-2,6-lutidine adduct 
Kivijärvi, L; Haukka, M 
2015 
71 
Pt 12 
o944 
English 
26870542 
In the title compound, C12H14BN, the complete mol-ecule is generated by a crystallographic twofold axis, with two C atoms, the B atom and the N atom lying on the rotation axis. The dihedral angle between the bora-benzene and pyridine rings is 81.20 (6)°. As well as dative electron donation from the N atom to the B atom [B-N = 1.5659 (18) Å], the methyl substituents on the lutidine ring shield the B atom, which further stabilizes the mol-ecule. In the crystal, weak aromatic π-π stacking between the pyridine rings [centroid-centroid separation = 3.6268 (9) Å] is observed, which generates [001] columns of mol-ecules.