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HERO ID
3389719
Reference Type
Journal Article
Title
THE HIGH-TEMPERATURE OXIDATION OF THE METHYL SIDE-CHAIN OF TOLUENE
Author(s)
Brezinsky, K; Litzinger, TA; Glassman, I
Year
1984
Is Peer Reviewed?
Yes
Journal
International Journal of Chemical Kinetics
ISSN:
0538-8066
EISSN:
1097-4601
Volume
16
Issue
9
Page Numbers
1053-1074
Language
English
DOI
10.1002/kin.550160902
Web of Science Id
WOS:A1984TG85400001
Abstract
From the results of order of magnitude analyses, it is concluded that during the oxidation of toluene, radicalâatom and radicalâradical reactions (1) and (3) play an unusually important and approximately equal role in the formation of benzaldehyde, an intermediate that leads eventually to the complete removal of the side chain. (Formula Presented.) An additional radicalâradical system, reaction (2), is shown to be the most likely source of benzyl alcohol observed during toluene oxidation. (Formula Presented.) Copyright © 1984 John Wiley & Sons, Inc.
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