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3418493 
Journal Article 
Combined effects of FeCl3 and CaO conditioning on SO2, HCl and heavy metals emissions during the DDSS incineration 
Liu, J; Zeng, J; Sun, S; Huang, S; Kuo, J; Chen, N 
2016 
Yes 
Chemical Engineering Journal
ISSN: 1385-8947 
299 
449-458 
WOS:000377832500050 
Batch incineration tests of sludge before and after conditioning were conducted in atmospheric conditions to investigate the emissions of SO2, HCl and heavy metals using a simulated laboratory tubular furnace reactor. The results show that when the temperature increased from 600 degrees C to 900 degrees C, the emissions of SO2 and HCl increased before sludge conditioning. After conditioning with FeCl3/CaO, the SO2 emissions was reduced and the conversion of Cl to HCI decreased, but HCI emissions increased. When the temperature was above 900 degrees C, the conditioner had a weak effect on fixing the S and Cl emission. After conditioning with FeCl3/CaO, Pb, Zn, and Cu concentrations in the bottom ash decreased, the volatility of Cu and Cr improved. Chlorine exhibited larger effects on the volatilization of heavy metals than did CaO. The consistency between the above experimental results and the model predictions based on a thermodynamic equilibrium analysis was confirmed. (C) 2016 Elsevier B.V. All rights reserved. 
FeCl3/CaO; Deep dewatered sewage sludge (DDSS); Combustion; HCl; SO2; Heavy metal