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Citation
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HERO ID
3577710
Reference Type
Journal Article
Title
High-yield exfoliation of graphite in acrylate polymers: A stable few-layer graphene nanofluid with enhanced thermal conductivity
Author(s)
Sun, Z; Poeller, S; Huang, X; Guschin, D; Taetz, C; Ebbinghaus, P; Masa, J; Erbe, A; Kilzer, A; Schuhmann, W; Muhler, M
Year
2013
Is Peer Reviewed?
Yes
Journal
Carbon
ISSN:
0008-6223
EISSN:
1873-3891
Volume
64
Page Numbers
288-294
DOI
10.1016/j.carbon.2013.07.063
Web of Science Id
WOS:000324898600033
Abstract
High-yield exfoliation of pristine graphite in low boiling point alcohols was achieved using a set of acrylate polymers resulting in few-layer graphene concentrations of up to similar to 4 mg mL(-1). The polymer showed superior dispersing capabilities for graphene compared to the best reported dispersants, including the solvent N-methyl-pyrrolidone, the surfactants sodium cholate and sodium taurodeoxycholate, and the polymer polyvinylpyrrolidone. The dispersions were stable regardless of freezing (-26 degrees C) or heating (70 degrees C) for 24 h, or dilution with water up to 80% volume ratio over 160 h. The as-obtained nanofluid exhibited an enhancement in thermal conductivity suggesting a great potential in coolant applications. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.
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OPPT REs
•
OPPT_N-methylpyrrolidone (NMP)_C. Engineering
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•
OPPT_N-methylpyrrolidone (NMP)_D. Exposure
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•
OPPT_N-methylpyrrolidone (NMP)_E. Fate
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