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Citation
Tags
HERO ID
3579271
Reference Type
Journal Article
Title
INCLUSION OF DIOXANE AND PYRIDINE BY A TRICYCLIC HOST STRUCTURES, KINETICS AND SELECTIVITY
Author(s)
Ramon, G; Jacobs, A; Molete, RP; Nassimbeni, LR; Taljaard, JH
Year
2009
Is Peer Reviewed?
Yes
Journal
Annales de Chimie: Science des Materiaux
ISSN:
0151-9107
Volume
34
Issue
6
Page Numbers
429-440
DOI
10.3166/acsm.34.429-440
Web of Science Id
WOS:000275824500009
Abstract
The host 10,11-dihydro-5-(1-naphthyl)-5H-dibenzo [a,d]cyclohepten-5-ol forms inclusion compounds with 1,4-dioxane and pyridine, with host:guest ratios of 1:1. The structures of the inclusion compounds as well as that of the apohost have been elucidated and their packing analysed. The stability of the inclusion compounds have been measured by DSC and the kinetics of desorption have been analysed. Competition experiments show that pyridine is preferentially enclathrated over dioxane over practically the whole range of pyridine/dioxane mixtures, with a selectivity constant K-pyr:diox approximate to 9.3.
Tags
OPPT REs
•
OPPT_1,4-Dioxane_C. Engineering
Data screening total
Screening: Excluded
•
OPPT_1,4-Dioxane_D. Exposure
Total – title/abstract screening
Off topic
Supplemental Search
Consumer Use
•
OPPT_1,4-Dioxane_E. Fate
Total – title/abstract screening
Off topic
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