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3586934 
Journal Article 
ELECTROCHEMICAL OXIDATION OF 1,3,5-TRIS(DIPHENYLAMINO)BENZENE (TDAB) FOR POLYRADICAL MATERIAL 
Yoshizawa, K; Ito, A; Tanaka, K; Yamabe, T 
1994 
1 
Synthetic Metals
ISSN: 0379-6779 
ELSEVIER SCIENCE SA LAUSANNE 
LAUSANNE 1 
66 
1 
81-83 
English 
WOS:A1994PF68200011 
Electrochemical coupling of 1,3,5-tris(diphenylamino)benzene (TDAB) occurs in dichloromethane or trichloroethane solution in the presence of tetrabutylammonium tetrafluoroborate or perchlorate. The obtained material contains radical cations, the spin concentration of which is of the order 10(19) g-1. An anodic reaction pathway of TDAB is proposed on the basis of the dimerization mechanism of the triphenylaminium radical cation. 
ELECTROCHEMICAL OXIDATION; POLYRADICAL MATERIAL; 1,3,5-TRIS(DIPHENYLAMINO)BENZENE